Model of a video-game and movie hero - Pikachu, a yellow cute) Everyone, who watched a movie or only heard about Pokemons, knows him.
In the Edit mode you can choose for every face a material. First, you choose faces, then creating material and Apply them to those faces.
https://blender.stackexchange.com/questions/516/add-different-materials-to-different-parts-of-a-mesh
I LOVE IT